$string = "PHP Programming";
$byteArray = unpack('C*', mb_convert_encoding($string, 'ISO-8859-1', 'UTF-8'));
print_r($byteArray);
/*
run:
Array
(
[1] => 80
[2] => 72
[3] => 80
[4] => 32
[5] => 80
[6] => 114
[7] => 111
[8] => 103
[9] => 114
[10] => 97
[11] => 109
[12] => 109
[13] => 105
[14] => 110
[15] => 103
)
*/